Rubyの最新版をhomebrewでインストール

$ brew update
$ brew upgrade ruby-build
$ brew install openssl curl-ca-bundle readline
$ cp /usr/local/Cellar/curl-ca-bundle/1.87/share/ca-bundle.crt /usr/local/etc/openssl/cert.pem #証明書のコピー
$ RUBY_CONFIGURE_OPTS="--with-readline-dir=`brew --prefix readline` --with-openssl-dir=`brew --prefix openssl`" rbenv install 2.0.0-p0

$ brew install rbenv
$ brew install ruby-build
$ echo 'eval "$(rbenv init -)"' >> .bash_profile 
$ source ~/.bash_profile
$ rbenv rehash

$ rbenv global 2.0.0-p0
$ ruby -v
ruby 2.0.0p0 (2013-02-24 revision 39474) [x86_64-darwin12.2.1]

参考 http://qiita.com/issobero/items/e0443b79da117ed48294